##TITLE=              31P MAS NMR spectrum of as-made AlPO-18 (with tetraethylammonium template)
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             He and Klinowski. J. Phys. Chem., 97, 10385-10388 (1993) Figure 2a
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University
##LONG DATE=          2020/07/13 11:12:14
##SOURCE REFERENCE=   AEI-31P-He-1993-asmade
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              AEI
##NAMES=              AlPO-18
##SAMPLE DESCRIPTION= AlPO-18, as-made

$$Bibliographic information 
##$AUTHORS=           He, H., Klinowski, J.
##$TITLE=             Solid state NMR studies of the aluminophosphate molecular sieve AlPO4-18
##$JOURNAL=           Journal of Physical Chemistry
##$VOLUME=            97
##$PAGES=             10385-10388
##$YEAR=              1993
##$DOI=               10.1021/j100142a020
##$FIGURE=            Figure 2a

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         3
##$PEAK LABELS=        P2         P1         P3        
##$PEAK TSITES=        T2         T3         T1        
##$PEAK POSITIONS=    -30.4006   -28.5517   -12.5726   
##$PEAK AREAS=         1.         1.         1.        
##$PEAK WIDTHS=        1.82309    1.84243    1.44386   
##$PEAK SHAPES=        0.33867    0.33867    0.33867   
##$NUMBERING REF=     Simmen et al. Zeolites, 11, 654-661 (1991)
##$ASSIGN REF=        He and Klinowski. J. Phys. Chem., 97, 10385-10388 (1993) Figure 2
##$ASSIGN METHOD=     average bond angles
##$COMMENT=           Peak assignments are tentative since they are based on local geometry around P atoms determined from PXRD

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^31P
##.OBSERVE FREQUENCY= 162.0
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     8000-10000

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -2.3                  
##LASTX=              -45.5                 
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            433
##FIRSTY=             -0.00710              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -2.3                -0.00710              
 -2.4                -0.00628              
 -2.5                -0.00555              
 -2.6                -0.00498              
 -2.7                -0.00529              
 -2.8                -0.00549              
 -2.9                -0.00548              
 -3.                 -0.00548              
 -3.1                -0.00548              
 -3.2                -0.00549              
 -3.3                -0.00507              
 -3.4                -0.00410              
 -3.5                -0.00313              
 -3.6                -0.00207              
 -3.7                -0.00135              
 -3.8                -0.00109              
 -3.9                -0.00110              
 -4.                 -0.00112              
 -4.1                -0.00161              
 -4.2                -0.00207              
 -4.3                -0.00208              
 -4.4                -0.00208              
 -4.5                -0.00215              
 -4.6                -0.00313              
 -4.7                -0.00356              
 -4.8                -0.00353              
 -4.9                -0.00354              
 -5.                 -0.00353              
 -5.1                -0.00355              
 -5.2                -0.00365              
 -5.3                -0.00314              
 -5.4                -0.00209              
 -5.5                -0.00094              
 -5.6                 0.00088              
 -5.7                 0.00314              
 -5.8                 0.00429              
 -5.9                 0.00422              
 -6.                  0.00425              
 -6.1                 0.00424              
 -6.2                 0.00425              
 -6.3                 0.00424              
 -6.4                 0.00425              
 -6.5                 0.00424              
 -6.6                 0.00377              
 -6.7                 0.00306              
 -6.8                 0.00279              
 -6.9                 0.00298              
 -7.                  0.00328              
 -7.1                 0.00327              
 -7.2                 0.00324              
 -7.3                 0.00296              
 -7.4                 0.00279              
 -7.5                 0.00306              
 -7.6                 0.00328              
 -7.7                 0.00327              
 -7.8                 0.00327              
 -7.9                 0.00328              
 -8.                  0.00285              
 -8.1                 0.00228              
 -8.2                 0.00230              
 -8.3                 0.00229              
 -8.4                 0.00230              
 -8.5                 0.00230              
 -8.6                 0.00230              
 -8.7                 0.00230              
 -8.8                 0.00230              
 -8.9                 0.00230              
 -9.                  0.00230              
 -9.1                 0.00229              
 -9.2                 0.00250              
 -9.3                 0.00299              
 -9.4                 0.00329              
 -9.5                 0.00363              
 -9.6                 0.00409              
 -9.7                 0.00426              
 -9.8                 0.00424              
 -9.9                 0.00425              
 -10.                 0.00453              
 -10.1                0.00548              
 -10.2                0.00618              
 -10.3                0.00684              
 -10.4                0.00845              
 -10.5                0.01030              
 -10.6                0.01288              
 -10.7                0.01568              
 -10.8                0.01854              
 -10.9                0.02139              
 -11.                 0.02598              
 -11.1                0.03499              
 -11.2                0.04757              
 -11.3                0.06040              
 -11.4                0.07688              
 -11.5                0.10712              
 -11.6                0.15018              
 -11.7                0.18952              
 -11.8                0.23975              
 -11.9                0.29998              
 -12.                 0.36513              
 -12.1                0.42219              
 -12.2                0.46796              
 -12.3                0.51641              
 -12.4                0.5487               
 -12.5                0.55572              
 -12.6                0.55794              
 -12.7                0.54575              
 -12.8                0.50909              
 -12.9                0.46909              
 -13.                 0.44979              
 -13.1                0.38752              
 -13.2                0.31495              
 -13.3                0.26768              
 -13.4                0.22440              
 -13.5                0.17009              
 -13.6                0.13084              
 -13.7                0.10961              
 -13.8                0.08569              
 -13.9                0.06571              
 -14.                 0.05064              
 -14.1                0.03927              
 -14.2                0.03329              
 -14.3                0.02811              
 -14.4                0.02391              
 -14.5                0.02155              
 -14.6                0.01983              
 -14.7                0.01793              
 -14.8                0.01583              
 -14.9                0.01397              
 -15.                 0.01209              
 -15.1                0.01090              
 -15.2                0.00985              
 -15.3                0.00871              
 -15.4                0.00793              
 -15.5                0.00692              
 -15.6                0.00580              
 -15.7                0.00468              
 -15.8                0.00391              
 -15.9                0.00320              
 -16.                 0.00252              
 -16.1                0.00254              
 -16.2                0.00324              
 -16.3                0.00394              
 -16.4                0.00465              
 -16.5                0.00523              
 -16.6                0.00522              
 -16.7                0.00521              
 -16.8                0.00481              
 -16.9                0.00383              
 -17.                 0.00324              
 -17.1                0.00328              
 -17.2                0.00327              
 -17.3                0.00327              
 -17.4                0.00327              
 -17.5                0.00328              
 -17.6                0.00306              
 -17.7                0.00256              
 -17.8                0.00159              
 -17.9                0.00068              
 -18.                 0.00032              
 -18.1                0.00036              
 -18.2                0.00034              
 -18.3                0.00036              
 -18.4                0.00061              
 -18.5                0.00108              
 -18.6                0.00132              
 -18.7                0.00134              
 -18.8                0.00092              
 -18.9               -0.00003              
 -19                 -0.00063              
 -19.1               -0.00060              
 -19.2               -0.00062              
 -19.3               -0.00061              
 -19.4               -0.00062              
 -19.5               -0.00060              
 -19.6               -0.00010              
 -19.7                0.00059              
 -19.8                0.00106              
 -19.9                0.00131              
 -20.                 0.00134              
 -20.1                0.00136              
 -20.2                0.00200              
 -20.3                0.00234              
 -20.4                0.00263              
 -20.5                0.00309              
 -20.6                0.00328              
 -20.7                0.00327              
 -20.8                0.00327              
 -20.9                0.00327              
 -21.                 0.00326              
 -21.1                0.00370              
 -21.2                0.00426              
 -21.3                0.00425              
 -21.4                0.00416              
 -21.5                0.00359              
 -21.6                0.00330              
 -21.7                0.00386              
 -21.8                0.00426              
 -21.9                0.00424              
 -22.                 0.00424              
 -22.1                0.00401              
 -22.2                0.00354              
 -22.3                0.00328              
 -22.4                0.00328              
 -22.5                0.00323              
 -22.6                0.00225              
 -22.7                0.00139              
 -22.8                0.00065              
 -22.9               -0.00023              
 -23.                -0.00034              
 -23.1                0.00014              
 -23.2                0.00061              
 -23.3                0.00155              
 -23.4                0.00318              
 -23.5                0.00463              
 -23.6                0.00521              
 -23.7                0.00486              
 -23.8                0.00430              
 -23.9                0.00362              
 -24.                 0.00319              
 -24.1                0.00270              
 -24.2                0.00226              
 -24.3                0.00203              
 -24.4                0.00156              
 -24.5                0.00132              
 -24.6                0.00132              
 -24.7                0.00132              
 -24.8                0.00133              
 -24.9                0.00132              
 -25.                 0.00095              
 -25.1                0.00052              
 -25.2                0.00071              
 -25.3                0.00178              
 -25.4                0.00335              
 -25.5                0.00494              
 -25.6                0.00572              
 -25.7                0.00665              
 -25.8                0.00916              
 -25.9                0.01225              
 -26.                 0.01510              
 -26.1                0.01789              
 -26.2                0.02030              
 -26.3                0.02438              
 -26.4                0.02837              
 -26.5                0.03265              
 -26.6                0.03869              
 -26.7                0.04534              
 -26.8                0.05201              
 -26.9                0.06059              
 -27.                 0.07344              
 -27.1                0.09108              
 -27.2                0.11160              
 -27.3                0.15068              
 -27.4                0.17680              
 -27.5                0.20347              
 -27.6                0.24074              
 -27.7                0.28123              
 -27.8                0.32243              
 -27.9                0.35640              
 -28.                 0.38602              
 -28.1                0.41658              
 -28.2                0.44332              
 -28.3                0.46501              
 -28.4                0.47908              
 -28.5                0.49387              
 -28.6                0.50029              
 -28.7                0.50113              
 -28.8                0.49759              
 -28.9                0.49115              
 -29.                 0.48119              
 -29.1                0.47180              
 -29.2                0.46514              
 -29.3                0.46022              
 -29.4                0.45846              
 -29.5                0.46205              
 -29.6                0.46997              
 -29.7                0.47707              
 -29.8                0.48846              
 -29.9                0.50327              
 -30.                 0.51350              
 -30.1                0.52031              
 -30.2                0.52475              
 -30.3                0.52229              
 -30.4                0.50959              
 -30.5                0.49080              
 -30.6                0.46776              
 -30.7                0.44246              
 -30.8                0.42402              
 -30.9                0.39459              
 -31.                 0.35456              
 -31.1                0.31749              
 -31.2                0.29060              
 -31.3                0.26383              
 -31.4                0.23291              
 -31.5                0.20125              
 -31.6                0.17000              
 -31.7                0.14815              
 -31.8                0.13146              
 -31.9                0.11174              
 -32.                 0.09121              
 -32.1                0.07518              
 -32.2                0.06668              
 -32.3                0.05979              
 -32.4                0.05526              
 -32.5                0.05032              
 -32.6                0.04598              
 -32.7                0.04228              
 -32.8                0.03879              
 -32.9                0.03622              
 -33.                 0.03412              
 -33.1                0.03215              
 -33.2                0.03104              
 -33.3                0.02879              
 -33.4                0.02729              
 -33.5                0.02581              
 -33.6                0.02450              
 -33.7                0.02360              
 -33.8                0.02235              
 -33.9                0.02046              
 -34.                 0.01885              
 -34.1                0.01791              
 -34.2                0.01697              
 -34.3                0.01647              
 -34.4                0.01547              
 -34.5                0.01394              
 -34.6                0.01399              
 -34.7                0.01363              
 -34.8                0.01320              
 -34.9                0.01297              
 -35.                 0.01247              
 -35.1                0.01203              
 -35.2                0.01204              
 -35.3                0.01204              
 -35.4                0.01183              
 -35.5                0.01135              
 -35.6                0.01102              
 -35.7                0.01038              
 -35.8                0.01008              
 -35.9                0.01007              
 -36.                 0.00976              
 -36.1                0.00899              
 -36.2                0.00792              
 -36.3                0.00702              
 -36.4                0.00668              
 -36.5                0.00622              
 -36.6                0.00573              
 -36.7                0.00570              
 -36.8                0.00572              
 -36.9                0.00605              
 -37.                 0.00652              
 -37.1                0.00669              
 -37.2                0.00668              
 -37.3                0.00667              
 -37.4                0.00670              
 -37.5                0.00720              
 -37.6                0.00790              
 -37.7                0.00814              
 -37.8                0.00814              
 -37.9                0.00814              
 -38.                 0.00813              
 -38.1                0.00815              
 -38.2                0.00874              
 -38.3                0.00883              
 -38.4                0.00865              
 -38.5                0.00921              
 -38.6                0.00988              
 -38.7                0.01009              
 -38.8                0.01009              
 -38.9                0.01009              
 -39.                 0.01009              
 -39.1                0.01009              
 -39.2                0.01009              
 -39.3                0.01009              
 -39.4                0.01009              
 -39.5                0.01009              
 -39.6                0.01009              
 -39.7                0.01009              
 -39.8                0.01009              
 -39.9                0.01009              
 -40.                 0.01009              
 -40.1                0.01009              
 -40.2                0.01009              
 -40.3                0.01009              
 -40.4                0.01009              
 -40.5                0.01009              
 -40.6                0.01010              
 -40.7                0.01006              
 -40.8                0.00979              
 -40.9                0.00928              
 -41.                 0.00858              
 -41.1                0.00800              
 -41.2                0.00730              
 -41.3                0.00670              
 -41.4                0.00667              
 -41.5                0.00668              
 -41.6                0.00689              
 -41.7                0.00770              
 -41.8                0.00833              
 -41.9                0.00934              
 -42.                 0.01015              
 -42.1                0.01005              
 -42.2                0.00955              
 -42.3                0.00885              
 -42.4                0.00839              
 -42.5                0.00782              
 -42.6                0.00701              
 -42.7                0.00612              
 -42.8                0.00569              
 -42.9                0.00571              
 -43.                 0.00570              
 -43.1                0.00570              
 -43.2                0.00571              
 -43.3                0.00570              
 -43.4                0.00543              
 -43.5                0.00496              
 -43.6                0.00473              
 -43.7                0.00473              
 -43.8                0.00473              
 -43.9                0.00473              
 -44.                 0.00473              
 -44.1                0.00473              
 -44.2                0.00472              
 -44.3                0.00475              
 -44.4                0.00467              
 -44.5                0.00374              
 -44.6                0.00261              
 -44.7                0.00230              
 -44.8                0.00230              
 -44.9                0.00230              
 -45.                 0.00229              
 -45.1                0.00228              
 -45.2                0.00195              
 -45.3                0.00184              
 -45.4                0.00214              
 -45.5                0.00246              
##END=
