##TITLE=              29Si MAS NMR spectrum of calcined dealuminated ZSM-12 (MTW)
##JCAMP-DX=           5.01
##DATA TYPE=          NMR SPECTRUM
##DATA CLASS=         XYDATA
##ORIGIN=             Fyfe et al. Zeolites, 8, 132-136 (1988) Figure 1a
##OWNER=              Digitized and processed by Brouwer Lab, Redeemer University College
##LONG DATE=          2019/06/20 16:20:01
##SOURCE REFERENCE=   MTW-29Si-Fyfe-1988
##DATA PROCESSING=    Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook

$$Sample information 
##NAMES=              MTW
##NAMES=              ZSM-12
##SAMPLE DESCRIPTION= ZSM-12, dealuminated

$$Bibliographic information 
##$AUTHORS=           Fyfe, C.A., Strobl, H., Kokotailo, G.T., Pasztor, C.T., Barlow, G.E., Bradley, S.
##$TITLE=             Correlations between lattice structures of zeolites and their 29Si MAS n.m.r. spectra: zeolites KZ-2, ZSM-12, and Beta
##$JOURNAL=           Zeolites
##$VOLUME=            8
##$PAGES=             132-136
##$YEAR=              1988
##$DOI=               10.1016/S0144-2449(88)80079-4
##$FIGURE=            Figure 1a

$$Peak information    (Positions in ppm, Relative peak areas, Peak widths in ppm, Lorentzian/Gaussian shape parameter)
##$NUM PEAKS=         7
##$PEAK TSITES=        T2         T5         T7         T2         T6         T4         T3        
##$PEAK LABELS=        Si2        Si5        Si7        Si2        Si6        Si4        Si3       
##$PEAK POSITIONS=    -112.483   -112.087   -111.153   -110.673   -108.848   -108.34    -107.643   
##$PEAK AREAS=         1.         1.         1.         1.         1.         1.         1.        
##$PEAK WIDTHS=        0.20803    0.22211    0.23167    0.22247    0.20255    0.22215    0.25544   
##$PEAK SHAPES=        0.74625    0.74625    0.74625    0.74625    0.74625    0.74625    0.74625   
##$NUMBERING REF=     Fyfe et al. J. Phys. Chem., 94, 3718-3721 (1990)
##$ASSIGN REF=        Fyfe et al. J. Am. Chem. Soc., 112, 3264-3270 (1990) Figure 7a
##$ASSIGN METHOD=     2D correlation NMR

$$Spectrum acquisition information 
##.OBSERVE NUCLEUS=   ^29Si
##.OBSERVE FREQUENCY= 79.5
##.PULSE SEQUENCE=    single pulse
##.MAS FREQUENCY=     

$$Spectrum data information 
##XUNITS=             PPM
##YUNITS=             ARBITRARY UNITS
##FIRSTX=             -104.83               
##LASTX=              -119.85               
##XFACTOR=            1
##YFACTOR=            1
##NPOINTS=            1503
##FIRSTY=              0.06665              

$$Spectrum data
##XYDATA=             (X++(Y..Y))
 -104.83              0.06665              
 -104.84              0.06112              
 -104.85              0.05329              
 -104.86              0.02227              
 -104.87             -0.00085              
 -104.88             -0.00097              
 -104.89              0.00055              
 -104.9               0.00330              
 -104.91              0.00361              
 -104.92              0.00269              
 -104.93              0.00636              
 -104.94              0.01101              
 -104.95              0.01104              
 -104.96              0.00968              
 -104.97              0.00970              
 -104.98              0.00954              
 -104.99              0.01075              
 -105.                0.01094              
 -105.01              0.00929              
 -105.02              0.01003              
 -105.03              0.01288              
 -105.04              0.01105              
 -105.05              0.01609              
 -105.06              0.02090              
 -105.07              0.02068              
 -105.08              0.02349              
 -105.09              0.02875              
 -105.1               0.02581              
 -105.11              0.02801              
 -105.12              0.02699              
 -105.13              0.02660              
 -105.14              0.02833              
 -105.15              0.02562              
 -105.16              0.02868              
 -105.17              0.02605              
 -105.18              0.02761              
 -105.19              0.02751              
 -105.2               0.02597              
 -105.21              0.02899              
 -105.22              0.02577              
 -105.23              0.01694              
 -105.24              0.01793              
 -105.25              0.01835              
 -105.26              0.01482              
 -105.27              0.01208              
 -105.28              0.01154              
 -105.29              0.01879              
 -105.3               0.01683              
 -105.31              0.01855              
 -105.32              0.02604              
 -105.33              0.02855              
 -105.34              0.02518              
 -105.35              0.02397              
 -105.36              0.02356              
 -105.37              0.01519              
 -105.38              0.00876              
 -105.39              0.00378              
 -105.4              -0.00164              
 -105.41              0.00020              
 -105.42             -0.00252              
 -105.43             -0.00323              
 -105.44             -0.00286              
 -105.45             -0.00300              
 -105.46             -0.00296              
 -105.47             -0.00298              
 -105.48             -0.00298              
 -105.49             -0.00283              
 -105.5              -0.00355              
 -105.51             -0.00047              
 -105.52              0.00501              
 -105.53              0.00641              
 -105.54              0.00342              
 -105.55              0.00016              
 -105.56              0.00274              
 -105.57              0.00162              
 -105.58              0.00118              
 -105.59              0.00299              
 -105.6               0.00023              
 -105.61              0.00335              
 -105.62              0.00021              
 -105.63              0.00551              
 -105.64              0.01091              
 -105.65              0.00927              
 -105.66              0.00999              
 -105.67              0.01276              
 -105.68              0.01530              
 -105.69              0.01884              
 -105.7               0.01749              
 -105.71              0.01695              
 -105.72              0.01894              
 -105.73              0.01606              
 -105.74              0.01904              
 -105.75              0.01695              
 -105.76              0.01634              
 -105.77              0.01369              
 -105.78              0.00916              
 -105.79              0.00968              
 -105.8               0.00949              
 -105.81              0.01496              
 -105.82              0.01611              
 -105.83              0.01776              
 -105.84              0.01842              
 -105.85              0.01629              
 -105.86              0.02240              
 -105.87              0.02853              
 -105.88              0.02525              
 -105.89              0.01789              
 -105.9               0.01683              
 -105.91              0.01933              
 -105.92              0.01561              
 -105.93              0.01006              
 -105.94              0.00944              
 -105.95              0.00983              
 -105.96              0.00967              
 -105.97              0.00972              
 -105.98              0.00971              
 -105.99              0.00971              
 -106.                0.00971              
 -106.01              0.00971              
 -106.02              0.00971              
 -106.03              0.00971              
 -106.04              0.00971              
 -106.05              0.00971              
 -106.06              0.00971              
 -106.07              0.00972              
 -106.08              0.00966              
 -106.09              0.00986              
 -106.1               0.00935              
 -106.11              0.01020              
 -106.12              0.01584              
 -106.13              0.01610              
 -106.14              0.01779              
 -106.15              0.02050              
 -106.16              0.02053              
 -106.17              0.02405              
 -106.18              0.03356              
 -106.19              0.03233              
 -106.2               0.03260              
 -106.21              0.03470              
 -106.22              0.03500              
 -106.23              0.03547              
 -106.24              0.03466              
 -106.25              0.02883              
 -106.26              0.03352              
 -106.27              0.03562              
 -106.28              0.03534              
 -106.29              0.03377              
 -106.3               0.02780              
 -106.31              0.02553              
 -106.32              0.02894              
 -106.33              0.02364              
 -106.34              0.02585              
 -106.35              0.02687              
 -106.36              0.02301              
 -106.37              0.02876              
 -106.38              0.02300              
 -106.39              0.02251              
 -106.4               0.01894              
 -106.41              0.01497              
 -106.42              0.01711              
 -106.43              0.01920              
 -106.44              0.01626              
 -106.45              0.01306              
 -106.46              0.01441              
 -106.47              0.01830              
 -106.48              0.01847              
 -106.49              0.01579              
 -106.5               0.01605              
 -106.51              0.01582              
 -106.52              0.01983              
 -106.53              0.02755              
 -106.54              0.02589              
 -106.55              0.02397              
 -106.56              0.03412              
 -106.57              0.03496              
 -106.58              0.03987              
 -106.59              0.04389              
 -106.6               0.04532              
 -106.61              0.04674              
 -106.62              0.04789              
 -106.63              0.04622              
 -106.64              0.03951              
 -106.65              0.03571              
 -106.66              0.04121              
 -106.67              0.04448              
 -106.68              0.04065              
 -106.69              0.04176              
 -106.7               0.04742              
 -106.71              0.04765              
 -106.72              0.05081              
 -106.73              0.05755              
 -106.74              0.06089              
 -106.75              0.06045              
 -106.76              0.06338              
 -106.77              0.07184              
 -106.78              0.07378              
 -106.79              0.07298              
 -106.8               0.07307              
 -106.81              0.07345              
 -106.82              0.07474              
 -106.83              0.07331              
 -106.84              0.07325              
 -106.85              0.07235              
 -106.86              0.07618              
 -106.87              0.07873              
 -106.88              0.07275              
 -106.89              0.07309              
 -106.9               0.07308              
 -106.91              0.07430              
 -106.92              0.07455              
 -106.93              0.07964              
 -106.94              0.08315              
 -106.95              0.07314              
 -106.96              0.07881              
 -106.97              0.07557              
 -106.98              0.07228              
 -106.99              0.07345              
 -107.                0.07303              
 -107.01              0.07519              
 -107.02              0.08217              
 -107.03              0.08474              
 -107.04              0.09153              
 -107.05              0.09776              
 -107.06              0.10219              
 -107.07              0.10889              
 -107.08              0.11122              
 -107.09              0.11097              
 -107.1               0.11455              
 -107.11              0.12323              
 -107.12              0.12764              
 -107.13              0.13320              
 -107.14              0.14995              
 -107.15              0.15551              
 -107.16              0.15700              
 -107.17              0.16538              
 -107.18              0.16680              
 -107.19              0.16765              
 -107.2               0.17933              
 -107.21              0.18218              
 -107.22              0.19566              
 -107.23              0.20477              
 -107.24              0.20878              
 -107.25              0.21638              
 -107.26              0.22778              
 -107.27              0.23913              
 -107.28              0.25159              
 -107.29              0.26568              
 -107.3               0.26898              
 -107.31              0.29398              
 -107.32              0.33996              
 -107.33              0.36334              
 -107.34              0.37811              
 -107.35              0.40320              
 -107.36              0.43303              
 -107.37              0.46042              
 -107.38              0.48435              
 -107.39              0.51902              
 -107.4               0.58093              
 -107.41              0.64520              
 -107.42              0.68261              
 -107.43              0.72750              
 -107.44              0.77661              
 -107.45              0.83762              
 -107.46              0.93963              
 -107.47              1.03316              
 -107.48              1.11814              
 -107.49              1.18737              
 -107.5               1.29819              
 -107.51              1.44009              
 -107.52              1.54986              
 -107.53              1.64938              
 -107.54              1.757                
 -107.55              1.9033               
 -107.56              2.07213              
 -107.57              2.2292               
 -107.58              2.34869              
 -107.59              2.42593              
 -107.6               2.49627              
 -107.61              2.59729              
 -107.62              2.71567              
 -107.63              2.81724              
 -107.64              2.86457              
 -107.65              2.86664              
 -107.66              2.8645               
 -107.67              2.79518              
 -107.68              2.76414              
 -107.69              2.65748              
 -107.7               2.50213              
 -107.71              2.39963              
 -107.72              2.25725              
 -107.73              2.10876              
 -107.74              1.96242              
 -107.75              1.81022              
 -107.76              1.66061              
 -107.77              1.51936              
 -107.78              1.38655              
 -107.79              1.27054              
 -107.8               1.1438               
 -107.81              1.02987              
 -107.82              0.95988              
 -107.83              0.89838              
 -107.84              0.81520              
 -107.85              0.75363              
 -107.86              0.70910              
 -107.87              0.66459              
 -107.88              0.62482              
 -107.89              0.59357              
 -107.9               0.56674              
 -107.91              0.54253              
 -107.92              0.51936              
 -107.93              0.49597              
 -107.94              0.48268              
 -107.95              0.47572              
 -107.96              0.46889              
 -107.97              0.46669              
 -107.98              0.46696              
 -107.99              0.45526              
 -108.                0.45809              
 -108.01              0.45673              
 -108.02              0.45714              
 -108.03              0.46671              
 -108.04              0.46669              
 -108.05              0.48971              
 -108.06              0.48939              
 -108.07              0.51724              
 -108.08              0.55039              
 -108.09              0.55810              
 -108.1               0.58431              
 -108.11              0.63448              
 -108.12              0.67778              
 -108.13              0.70666              
 -108.14              0.74229              
 -108.15              0.82780              
 -108.16              0.94532              
 -108.17              1.02026              
 -108.18              1.08608              
 -108.19              1.16216              
 -108.2               1.29304              
 -108.21              1.49076              
 -108.22              1.66029              
 -108.23              1.76237              
 -108.24              1.94431              
 -108.25              2.10285              
 -108.26              2.27671              
 -108.27              2.51553              
 -108.28              2.74678              
 -108.29              2.89006              
 -108.3               2.98966              
 -108.31              3.10995              
 -108.32              3.2739               
 -108.33              3.33184              
 -108.34              3.36008              
 -108.35              3.3701               
 -108.36              3.21901              
 -108.37              3.16621              
 -108.38              3.02114              
 -108.39              2.91003              
 -108.4               2.76903              
 -108.41              2.5336               
 -108.42              2.34358              
 -108.43              2.17667              
 -108.44              1.93233              
 -108.45              1.8042               
 -108.46              1.63848              
 -108.47              1.46899              
 -108.48              1.3847               
 -108.49              1.20968              
 -108.5               1.14872              
 -108.51              1.07725              
 -108.52              0.99625              
 -108.53              0.94078              
 -108.54              0.89661              
 -108.55              0.85268              
 -108.56              0.81067              
 -108.57              0.79297              
 -108.58              0.76729              
 -108.59              0.7474               
 -108.6               0.74361              
 -108.61              0.74331              
 -108.62              0.75987              
 -108.63              0.79613              
 -108.64              0.84547              
 -108.65              0.87546              
 -108.66              0.91875              
 -108.67              0.97599              
 -108.68              1.02986              
 -108.69              1.18772              
 -108.7               1.31634              
 -108.71              1.42673              
 -108.72              1.5031               
 -108.73              1.64162              
 -108.74              1.89817              
 -108.75              2.07316              
 -108.76              2.28431              
 -108.77              2.49219              
 -108.78              2.64766              
 -108.79              2.83742              
 -108.8               3.04609              
 -108.81              3.19268              
 -108.82              3.47166              
 -108.83              3.56198              
 -108.84              3.65295              
 -108.85              3.68681              
 -108.86              3.59044              
 -108.87              3.52892              
 -108.88              3.39517              
 -108.89              3.19412              
 -108.9               2.97591              
 -108.91              2.73486              
 -108.92              2.52754              
 -108.93              2.33605              
 -108.94              2.05192              
 -108.95              1.86491              
 -108.96              1.666                
 -108.97              1.51992              
 -108.98              1.38343              
 -108.99              1.20576              
 -109.                1.07492              
 -109.01              0.95993              
 -109.02              0.89828              
 -109.03              0.80363              
 -109.04              0.71596              
 -109.05              0.66205              
 -109.06              0.60350              
 -109.07              0.56488              
 -109.08              0.49381              
 -109.09              0.45639              
 -109.1               0.43205              
 -109.11              0.40084              
 -109.12              0.38050              
 -109.13              0.36471              
 -109.14              0.34674              
 -109.15              0.32142              
 -109.16              0.29694              
 -109.17              0.28040              
 -109.18              0.27064              
 -109.19              0.25968              
 -109.2               0.24257              
 -109.21              0.23243              
 -109.22              0.22314              
 -109.23              0.21573              
 -109.24              0.20842              
 -109.25              0.19864              
 -109.26              0.19374              
 -109.27              0.19143              
 -109.28              0.18436              
 -109.29              0.17671              
 -109.3               0.17447              
 -109.31              0.17227              
 -109.32              0.16105              
 -109.33              0.14640              
 -109.34              0.14016              
 -109.35              0.13945              
 -109.36              0.13503              
 -109.37              0.12873              
 -109.38              0.12475              
 -109.39              0.11786              
 -109.4               0.11237              
 -109.41              0.10713              
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 -109.45              0.09214              
 -109.46              0.09482              
 -109.47              0.09663              
 -109.48              0.09808              
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 -109.5               0.09700              
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 -109.53              0.09332              
 -109.54              0.09179              
 -109.55              0.09170              
 -109.56              0.08625              
 -109.57              0.07833              
 -109.58              0.07316              
 -109.59              0.06714              
 -109.6               0.06919              
 -109.61              0.06827              
 -109.62              0.06781              
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 -109.66              0.06729              
 -109.67              0.06889              
 -109.68              0.06854              
 -109.69              0.06785              
 -109.7               0.07384              
 -109.71              0.07478              
 -109.72              0.07333              
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 -109.75              0.06828              
 -109.76              0.06729              
 -109.77              0.06996              
 -109.78              0.06692              
 -109.79              0.06941              
 -109.8               0.06805              
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 -109.82              0.06933              
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 -109.87              0.08325              
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 -109.89              0.08590              
 -109.9               0.08582              
 -109.91              0.08272              
 -109.92              0.08480              
 -109.93              0.07829              
 -109.94              0.07225              
 -109.95              0.07569              
 -109.96              0.07614              
 -109.97              0.07323              
 -109.98              0.07529              
 -109.99              0.07835              
 -110.                0.08101              
 -110.01              0.08327              
 -110.02              0.08448              
 -110.03              0.08583              
 -110.04              0.08601              
 -110.05              0.08526              
 -110.06              0.08874              
 -110.07              0.09416              
 -110.08              0.09501              
 -110.09              0.09205              
 -110.1               0.09186              
 -110.11              0.09582              
 -110.12              0.09800              
 -110.13              0.09997              
 -110.14              0.10866              
 -110.15              0.11796              
 -110.16              0.11737              
 -110.17              0.12843              
 -110.18              0.14040              
 -110.19              0.14377              
 -110.2               0.14246              
 -110.21              0.14357              
 -110.22              0.14949              
 -110.23              0.15575              
 -110.24              0.15021              
 -110.25              0.15438              
 -110.26              0.16368              
 -110.27              0.17155              
 -110.28              0.18486              
 -110.29              0.19473              
 -110.3               0.21134              
 -110.31              0.22415              
 -110.32              0.23709              
 -110.33              0.25717              
 -110.34              0.27440              
 -110.35              0.28244              
 -110.36              0.30500              
 -110.37              0.33825              
 -110.38              0.35842              
 -110.39              0.38228              
 -110.4               0.41473              
 -110.41              0.43289              
 -110.42              0.45944              
 -110.43              0.50897              
 -110.44              0.56968              
 -110.45              0.62080              
 -110.46              0.65309              
 -110.47              0.69637              
 -110.48              0.78581              
 -110.49              0.87053              
 -110.5               0.93964              
 -110.51              1.03778              
 -110.52              1.11943              
 -110.53              1.23389              
 -110.54              1.46394              
 -110.55              1.59895              
 -110.56              1.75854              
 -110.57              1.8855               
 -110.58              2.07053              
 -110.59              2.33976              
 -110.6               2.55188              
 -110.61              2.71632              
 -110.62              2.89124              
 -110.63              2.98213              
 -110.64              3.11645              
 -110.65              3.22315              
 -110.66              3.26652              
 -110.67              3.39748              
 -110.68              3.33424              
 -110.69              3.3328               
 -110.7               3.2281               
 -110.71              3.0992               
 -110.72              3.00413              
 -110.73              2.77479              
 -110.74              2.56416              
 -110.75              2.4106               
 -110.76              2.21919              
 -110.77              2.06327              
 -110.78              1.91096              
 -110.79              1.72257              
 -110.8               1.63029              
 -110.81              1.50685              
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##END=
