Database of Zeolite Structures
 

Framework Type CZP
Reference Material
  Material Name: Chiral Zincophosphate    
 
Chemical Formula:
 
|Na12 (H2O)12 | [Zn12P12O48]-CZP
 
   
Unit Cell:§
 
hexagonal

 P 61 2 2 (# 178)
    a' = 10.4800 Å b' = 10.4800 Å c' = 15.0890 Å  
    α' = 90.000° β' = 90.000° γ' = 120.000°  
   
Framework Density:
 
16.7 T/1000 Å3
 
 
Channels:
 
[001] 12 3.8 x 7.2* (highly distorted 12-ring)
Dimensionality
  Sorption (molecular cross section > 3.4Å): 1-dimensional
  Topological (pore opening > 6-ring): 1-dimensional
   
References:
  Rajic, N., Logar, N.Z. and Kaucic, V.
  "A novel open framework zincophosphate: Synthesis and characterization"
Zeolites, 15, 672-678 (1995)
Material name:   Chiral Zincophosphate
Chemical formula:   [Zn12P12O48]-CZP
  § Harrison, W.T.A., Gier, T.E., Stucky, G.D., Broach, R.W. and Bedard, R.A.
  "NaZnPO4·H2O, an open-framework sodium zincophosphate with a new chiral tetrahedral framework topology"
Chem. Mater., 8, 145-151 (1996)
 
 
Name and Code derivation:
    Chiral Zincophosphate
  CZP
 
 
§ Chemical Formula and Unit Cell taken from the reference marked with this sign
Limiting Rings
 
distorted 12-ring viewed along [001]