29Si MAS NMR spectrum of as-synthesized zeolite L ##freq 1 ##ppm spectr model Q4(3Al) Q4(2Al) Q4(1Al) Q4(0Al) ----- -79.1 0.2616 0.2603 0 0 0 0 -79.2 0.2627 0.2603 0 0 0 0 -79.3 0.2642 0.2603 0 0 0 0 -79.4 0.2638 0.2603 0 0 0 0 -79.5 0.2644 0.2603 0 0 0 0 -79.6 0.2654 0.2603 0 0 0 0 -79.7 0.2653 0.2603 0 0 0 0 -79.8 0.2653 0.2603 0 0 0 0 -79.9 0.2653 0.2603 0 0 0 0 -80 0.2652 0.2603 0 0 0 0 -80.1 0.2644 0.2603 0 0 0 0 -80.2 0.2649 0.2603 0 0 0 0 -80.3 0.2645 0.2603 0 0 0 0 -80.4 0.2637 0.2603 0 0 0 0 -80.5 0.2636 0.2603 0 0 0 0 -80.6 0.2635 0.2603 0 0 0 0 -80.7 0.2651 0.2603 0 0 0 0 -80.8 0.2653 0.2603 0 0 0 0 -80.9 0.2653 0.2603 0 0 0 0 -81 0.2662 0.2602 0 0 0 0 -81.1 0.2654 0.2602 0 0 0 0 -81.2 0.2653 0.2602 0 0 0 0 -81.3 0.266 0.2602 0 0 0 0 -81.4 0.2661 0.2602 0 0 0 0 -81.5 0.2661 0.2602 0 0 0 0 -81.6 0.2653 0.2602 0 0 0 0 -81.7 0.2653 0.2602 0 0 0 0 -81.8 0.2653 0.2602 0 0 0 0 -81.9 0.2644 0.2602 0 0 0 0 -82 0.2641 0.2602 0 0 0 0 -82.1 0.2637 0.2602 0 0 0 0 -82.2 0.2637 0.2602 0 0 0 0 -82.3 0.2626 0.2602 0 0 0 0 -82.4 0.2636 0.2602 0 0 0 0 -82.5 0.2657 0.2602 0 0 0 0 -82.6 0.2662 0.2602 0 0 0 0 -82.7 0.2662 0.2602 0 0 0 0 -82.8 0.2685 0.2602 0 0 0 0 -82.9 0.2696 0.2602 0 0 0 0 -83 0.2705 0.2602 0 0 0 0 -83.1 0.2708 0.2602 0 0 0 0 -83.2 0.2713 0.2602 0 0 0 0 -83.3 0.2722 0.2602 0 0 0 0 -83.4 0.2733 0.2602 0 0 0 0 -83.5 0.2733 0.2602 0 0 0 0 -83.6 0.2728 0.2602 0 0 0 0 -83.7 0.2698 0.2602 0 0 0 0 -83.8 0.269 0.2602 0 0 0 0 -83.9 0.2679 0.2602 0 0 0 0 -84 0.2681 0.2602 0 0 0 0 -84.1 0.2669 0.2602 0 0 0 0 -84.2 0.2661 0.2602 0 0 0 0 -84.3 0.2671 0.2602 0 0 0 0 -84.4 0.2669 0.2602 0 0 0 0 -84.5 0.2677 0.2602 0 0 0 0 -84.6 0.2692 0.2602 0 0 0 0 -84.7 0.2708 0.2602 0 0 0 0 -84.8 0.2739 0.2602 0 0 0 0 -84.9 0.274 0.2602 0 0 0 0 -85 0.274 0.2602 0 0 0 0 -85.1 0.2739 0.2602 0 0 0 0 -85.2 0.2736 0.2602 0 0 0 0 -85.3 0.2731 0.2602 0 0 0 0 -85.4 0.2718 0.2602 0 0 0 0 -85.5 0.2716 0.2602 0 0 0 0 -85.6 0.2696 0.2602 0 0 0 0 -85.7 0.2673 0.2602 0 0 0 0 -85.8 0.2661 0.2602 0 0 0 0 -85.9 0.2662 0.2602 0.0001 0 0 0 -86 0.2656 0.2602 0.0001 0 0 0 -86.1 0.2641 0.2602 0.0001 0 0 0 -86.2 0.2636 0.2602 0.0001 0 0 0 -86.3 0.2651 0.2603 0.0001 0 0 0 -86.4 0.2653 0.2603 0.0002 0 0 0 -86.5 0.2662 0.2603 0.0002 0 0 0 -86.6 0.2668 0.2604 0.0003 0 0 0 -86.7 0.2672 0.2604 0.0003 0 0 0 -86.8 0.2696 0.2605 0.0004 0 0 0 -86.9 0.2714 0.2606 0.0005 0 0 0 -87 0.2724 0.2607 0.0006 0 0 0 -87.1 0.2727 0.2608 0.0007 0 0 0 -87.2 0.2725 0.2609 0.0008 0 0 0 -87.3 0.2722 0.2611 0.001 0 0 0 -87.4 0.2726 0.2612 0.0011 0 0 0 -87.5 0.2725 0.2614 0.0013 0 0 0 -87.6 0.2711 0.2617 0.0016 0 0 0 -87.7 0.2705 0.262 0.0019 0 0 0 -87.8 0.2705 0.2623 0.0022 0 0 0 -87.9 0.2705 0.2626 0.0025 0 0 0 -88 0.2705 0.263 0.0029 0 0 0 -88.1 0.2705 0.2635 0.0034 0 0 0 -88.2 0.2706 0.264 0.0039 0 0 0 -88.3 0.2716 0.2646 0.0045 0 0 0 -88.4 0.2715 0.2653 0.0052 0 0 0 -88.5 0.2727 0.266 0.0059 0 0 0 -88.6 0.2746 0.2668 0.0068 0 0 0 -88.7 0.2787 0.2678 0.0077 0 0 0 -88.8 0.279 0.2688 0.0087 0 0 0 -88.9 0.2789 0.2699 0.0098 0 0 0 -89 0.2796 0.2711 0.011 0 0 0 -89.1 0.2802 0.2724 0.0123 0 0 0 -89.2 0.2836 0.2738 0.0137 0 0 0 -89.3 0.2846 0.2753 0.0153 0 0 0 -89.4 0.2854 0.277 0.0169 0 0 0 -89.5 0.2885 0.2787 0.0187 0 0 0 -89.6 0.2916 0.2806 0.0205 0 0 0 -89.7 0.293 0.2826 0.0225 0 0 0 -89.8 0.2934 0.2847 0.0246 0 0 0 -89.9 0.2962 0.2869 0.0268 0.0001 0 0 -90 0.2982 0.2891 0.029 0.0001 0 0 -90.1 0.2997 0.2915 0.0314 0.0001 0 0 -90.2 0.3006 0.294 0.0338 0.0001 0 0 -90.3 0.3025 0.2965 0.0363 0.0001 0 0 -90.4 0.3032 0.299 0.0388 0.0002 0 0 -90.5 0.3082 0.3017 0.0414 0.0002 0 0 -90.6 0.3103 0.3043 0.044 0.0003 0 0 -90.7 0.3122 0.307 0.0466 0.0003 0 0 -90.8 0.3169 0.3096 0.0492 0.0004 0 0 -90.9 0.318 0.3123 0.0517 0.0005 0 0 -91 0.3199 0.3149 0.0542 0.0007 0 0 -91.1 0.3216 0.3174 0.0566 0.0008 0 0 -91.2 0.3247 0.3199 0.0589 0.001 0 0 -91.3 0.3265 0.3223 0.061 0.0013 0 0 -91.4 0.3307 0.3247 0.0631 0.0016 0 0 -91.5 0.3331 0.3269 0.065 0.0019 0 0 -91.6 0.3333 0.329 0.0667 0.0023 0 0 -91.7 0.339 0.331 0.0682 0.0028 0 0 -91.8 0.3427 0.3329 0.0695 0.0034 0 0 -91.9 0.3457 0.3347 0.0706 0.0041 0 0 -92 0.3474 0.3364 0.0715 0.0049 0 0 -92.1 0.3474 0.3379 0.0721 0.0059 0 0 -92.2 0.3488 0.3394 0.0725 0.007 0 0 -92.3 0.3492 0.3409 0.0726 0.0083 0 0 -92.4 0.3501 0.3422 0.0725 0.0098 0 0 -92.5 0.3503 0.3436 0.0721 0.0115 0 0 -92.6 0.3518 0.345 0.0715 0.0135 0 0 -92.7 0.3517 0.3464 0.0706 0.0158 0 0 -92.8 0.3517 0.3479 0.0695 0.0184 0 0 -92.9 0.3517 0.3495 0.0682 0.0214 0 0 -93 0.3507 0.3514 0.0667 0.0247 0 0 -93.1 0.3515 0.3534 0.065 0.0284 0 0 -93.2 0.3555 0.3557 0.0631 0.0327 0 0 -93.3 0.3558 0.3584 0.061 0.0374 0 0 -93.4 0.3565 0.3614 0.0589 0.0426 0 0 -93.5 0.3624 0.3649 0.0566 0.0483 0 0 -93.6 0.3718 0.3688 0.0542 0.0547 0 0 -93.7 0.3801 0.3733 0.0517 0.0617 0 0 -93.8 0.3854 0.3784 0.0492 0.0692 0 0 -93.9 0.3858 0.384 0.0466 0.0775 0 0 -94 0.3978 0.3904 0.044 0.0864 0 0 -94.1 0.4059 0.3973 0.0414 0.096 0 0 -94.2 0.4207 0.405 0.0388 0.1062 0 0 -94.3 0.4383 0.4134 0.0363 0.1172 0 0 -94.4 0.431 0.4225 0.0338 0.1288 0 0 -94.5 0.4474 0.4323 0.0314 0.141 0 0 -94.6 0.4571 0.4428 0.029 0.1538 0 0 -94.7 0.4651 0.4538 0.0268 0.1672 0 0 -94.8 0.4803 0.4655 0.0246 0.181 0 0 -94.9 0.4925 0.4778 0.0225 0.1953 0 0 -95 0.5015 0.4904 0.0205 0.21 0 0 -95.1 0.5304 0.5035 0.0187 0.2249 0 0 -95.2 0.5269 0.5169 0.0169 0.2401 0 0 -95.3 0.5439 0.5305 0.0153 0.2553 0 0 -95.4 0.5508 0.5442 0.0137 0.2705 0 0 -95.5 0.5779 0.5578 0.0123 0.2855 0 0 -95.6 0.5907 0.5713 0.011 0.3003 0.0001 0 -95.7 0.5997 0.5845 0.0098 0.3147 0.0001 0 -95.8 0.6098 0.5973 0.0087 0.3286 0.0001 0 -95.9 0.6287 0.6096 0.0077 0.3419 0.0001 0 -96 0.6424 0.6213 0.0068 0.3544 0.0002 0 -96.1 0.6426 0.6321 0.0059 0.3661 0.0002 0 -96.2 0.659 0.6421 0.0052 0.3767 0.0003 0 -96.3 0.6648 0.651 0.0045 0.3862 0.0004 0 -96.4 0.6752 0.6589 0.0039 0.3946 0.0005 0 -96.5 0.6754 0.6655 0.0034 0.4016 0.0006 0 -96.6 0.6742 0.6709 0.0029 0.4073 0.0008 0 -96.7 0.679 0.675 0.0025 0.4116 0.001 0 -96.8 0.6807 0.6777 0.0022 0.4144 0.0012 0 -96.9 0.6809 0.6789 0.0019 0.4157 0.0015 0 -97 0.6765 0.6788 0.0016 0.4154 0.0019 0 -97.1 0.6746 0.6774 0.0013 0.4137 0.0024 0 -97.2 0.6739 0.6745 0.0011 0.4105 0.003 0 -97.3 0.6671 0.6704 0.001 0.4058 0.0037 0 -97.4 0.6574 0.665 0.0008 0.3997 0.0046 0 -97.5 0.6519 0.6585 0.0007 0.3923 0.0056 0 -97.6 0.6477 0.6509 0.0006 0.3836 0.0068 0 -97.7 0.6374 0.6424 0.0005 0.3738 0.0083 0 -97.8 0.6243 0.6331 0.0004 0.3628 0.01 0 -97.9 0.6151 0.6232 0.0003 0.3509 0.012 0 -98 0.5944 0.6128 0.0003 0.3382 0.0144 0 -98.1 0.5967 0.602 0.0002 0.3247 0.0172 0 -98.2 0.5938 0.5912 0.0002 0.3107 0.0205 0 -98.3 0.5788 0.5803 0.0001 0.2961 0.0242 0 -98.4 0.5656 0.5697 0.0001 0.2813 0.0285 0 -98.5 0.5494 0.5595 0.0001 0.2662 0.0334 0 -98.6 0.5491 0.5498 0.0001 0.2509 0.0389 0 -98.7 0.5444 0.5409 0.0001 0.2357 0.0452 0 -98.8 0.5334 0.5328 0 0.2207 0.0523 0 -98.9 0.5293 0.5258 0 0.2058 0.0602 0 -99 0.5212 0.52 0 0.1912 0.069 0 -99.1 0.5244 0.5156 0 0.177 0.0787 0 -99.2 0.5246 0.5125 0 0.1633 0.0894 0 -99.3 0.5191 0.511 0 0.1501 0.101 0 -99.4 0.5233 0.511 0 0.1374 0.1137 0 -99.5 0.5235 0.5127 0 0.1254 0.1275 0 -99.6 0.528 0.516 0 0.114 0.1422 0 -99.7 0.5254 0.521 0 0.1033 0.1579 0 -99.8 0.5328 0.5277 0 0.0932 0.1746 0 -99.9 0.5423 0.5359 0 0.0838 0.1922 0 -100 0.5449 0.5456 0 0.0751 0.2107 0 -100.1 0.5693 0.5567 0 0.067 0.2299 0 -100.2 0.5707 0.5691 0 0.0596 0.2497 0 -100.3 0.5969 0.5826 0 0.0528 0.27 0 -100.4 0.6096 0.5971 0 0.0466 0.2906 0 -100.5 0.6096 0.6123 0 0.041 0.3114 0 -100.6 0.6348 0.6281 0 0.036 0.3323 0 -100.7 0.654 0.6442 0 0.0314 0.3529 0 -100.8 0.6733 0.6604 0 0.0273 0.3732 0 -100.9 0.6856 0.6764 0 0.0237 0.3929 0 -101 0.6988 0.6921 0 0.0205 0.4118 0 -101.1 0.7241 0.7071 0 0.0176 0.4296 0 -101.2 0.7427 0.7212 0 0.0151 0.4462 0.0001 -101.3 0.7549 0.7342 0 0.0129 0.4614 0.0001 -101.4 0.7475 0.7459 0 0.011 0.475 0.0001 -101.5 0.7709 0.7561 0 0.0093 0.4868 0.0001 -101.6 0.7731 0.7646 0 0.0079 0.4967 0.0002 -101.7 0.7837 0.7712 0 0.0066 0.5046 0.0002 -101.8 0.7853 0.7758 0 0.0056 0.5102 0.0003 -101.9 0.7855 0.7784 0 0.0047 0.5137 0.0003 -102 0.7858 0.7789 0 0.0039 0.5148 0.0004 -102.1 0.779 0.7772 0 0.0032 0.5137 0.0005 -102.2 0.768 0.7733 0 0.0027 0.5102 0.0006 -102.3 0.771 0.7673 0 0.0022 0.5046 0.0008 -102.4 0.7658 0.7593 0 0.0018 0.4967 0.001 -102.5 0.7473 0.7493 0 0.0015 0.4868 0.0012 -102.6 0.7283 0.7374 0 0.0012 0.475 0.0014 -102.7 0.7112 0.7239 0 0.001 0.4614 0.0017 -102.8 0.7033 0.7089 0 0.0008 0.4462 0.0021 -102.9 0.6906 0.6925 0 0.0006 0.4296 0.0025 -103 0.6675 0.675 0 0.0005 0.4118 0.003 -103.1 0.6334 0.6567 0 0.0004 0.3929 0.0036 -103.2 0.62 0.6376 0 0.0003 0.3732 0.0043 -103.3 0.6147 0.618 0 0.0003 0.3529 0.0051 -103.4 0.5953 0.5982 0 0.0002 0.3323 0.006 -103.5 0.5655 0.5784 0 0.0002 0.3114 0.007 -103.6 0.554 0.5587 0 0.0001 0.2906 0.0082 -103.7 0.5267 0.5394 0 0.0001 0.27 0.0096 -103.8 0.525 0.5206 0 0.0001 0.2497 0.0111 -103.9 0.513 0.5025 0 0.0001 0.2299 0.0128 -104 0.4949 0.4852 0 0 0.2107 0.0147 -104.1 0.4785 0.4689 0 0 0.1922 0.0169 -104.2 0.4689 0.4536 0 0 0.1746 0.0192 -104.3 0.4678 0.4395 0 0 0.1579 0.0219 -104.4 0.443 0.4267 0 0 0.1422 0.0247 -104.5 0.4324 0.4151 0 0 0.1275 0.0279 -104.6 0.4208 0.4047 0 0 0.1137 0.0313 -104.7 0.4166 0.3957 0 0 0.101 0.035 -104.8 0.4154 0.388 0 0 0.0894 0.0389 -104.9 0.4058 0.3816 0 0 0.0787 0.0432 -105 0.3982 0.3764 0 0 0.069 0.0477 -105.1 0.3882 0.3723 0 0 0.0602 0.0524 -105.2 0.3868 0.3694 0 0 0.0523 0.0575 -105.3 0.3861 0.3676 0 0 0.0452 0.0627 -105.4 0.3844 0.3667 0 0 0.0389 0.0681 -105.5 0.3821 0.3668 0 0 0.0334 0.0737 -105.6 0.3807 0.3676 0 0 0.0285 0.0794 -105.7 0.3784 0.3692 0 0 0.0242 0.0853 -105.8 0.3785 0.3713 0 0 0.0205 0.0912 -105.9 0.379 0.374 0 0 0.0172 0.0971 -106 0.3805 0.3771 0 0 0.0144 0.103 -106.1 0.3811 0.3805 0 0 0.012 0.1087 -106.2 0.382 0.3841 0 0 0.01 0.1144 -106.3 0.383 0.3878 0 0 0.0083 0.1198 -106.4 0.3852 0.3915 0 0 0.0068 0.125 -106.5 0.3867 0.3952 0 0 0.0056 0.13 -106.6 0.3893 0.3987 0 0 0.0046 0.1345 -106.7 0.393 0.402 0 0 0.0037 0.1387 -106.8 0.393 0.405 0 0 0.003 0.1424 -106.9 0.3945 0.4076 0 0 0.0024 0.1456 -107 0.4011 0.4098 0 0 0.0019 0.1482 -107.1 0.3994 0.4116 0 0 0.0015 0.1504 -107.2 0.4002 0.4128 0 0 0.0012 0.1519 -107.3 0.4046 0.4134 0 0 0.001 0.1528 -107.4 0.4091 0.4135 0 0 0.0008 0.1531 -107.5 0.4087 0.4131 0 0 0.0006 0.1528 -107.6 0.4078 0.412 0 0 0.0005 0.1519 -107.7 0.4076 0.4104 0 0 0.0004 0.1504 -107.8 0.406 0.4082 0 0 0.0003 0.1482 -107.9 0.403 0.4054 0 0 0.0002 0.1456 -108 0.3975 0.4022 0 0 0.0002 0.1424 -108.1 0.3945 0.3984 0 0 0.0001 0.1387 -108.2 0.3939 0.3942 0 0 0.0001 0.1345 -108.3 0.3869 0.3897 0 0 0.0001 0.13 -108.4 0.3763 0.3847 0 0 0.0001 0.125 -108.5 0.3697 0.3795 0 0 0 0.1198 -108.6 0.3579 0.374 0 0 0 0.1144 -108.7 0.3643 0.3684 0 0 0 0.1087 -108.8 0.3583 0.3626 0 0 0 0.103 -108.9 0.3441 0.3567 0 0 0 0.0971 -109 0.3348 0.3508 0 0 0 0.0912 -109.1 0.33 0.3449 0 0 0 0.0853 -109.2 0.3304 0.3391 0 0 0 0.0794 -109.3 0.3257 0.3333 0 0 0 0.0737 -109.4 0.3144 0.3277 0 0 0 0.0681 -109.5 0.3106 0.3223 0 0 0 0.0627 -109.6 0.3078 0.3171 0 0 0 0.0575 -109.7 0.3068 0.312 0 0 0 0.0525 -109.8 0.3032 0.3073 0 0 0 0.0477 -109.9 0.3001 0.3028 0 0 0 0.0432 -110 0.2951 0.2985 0 0 0 0.0389 -110.1 0.2936 0.2946 0 0 0 0.035 -110.2 0.2906 0.2909 0 0 0 0.0313 -110.3 0.2911 0.2875 0 0 0 0.0279 -110.4 0.2873 0.2843 0 0 0 0.0247 -110.5 0.2837 0.2814 0 0 0 0.0219 -110.6 0.2819 0.2788 0 0 0 0.0192 -110.7 0.279 0.2764 0 0 0 0.0169 -110.8 0.2776 0.2743 0 0 0 0.0147 -110.9 0.2762 0.2724 0 0 0 0.0128 -111 0.2738 0.2707 0 0 0 0.0111 -111.1 0.2724 0.2691 0 0 0 0.0096 -111.2 0.2724 0.2678 0 0 0 0.0082 -111.3 0.2714 0.2666 0 0 0 0.007 -111.4 0.2699 0.2656 0 0 0 0.006 -111.5 0.2706 0.2646 0 0 0 0.0051 -111.6 0.2705 0.2639 0 0 0 0.0043 -111.7 0.2705 0.2632 0 0 0 0.0036 -111.8 0.2705 0.2626 0 0 0 0.003 -111.9 0.2705 0.2621 0 0 0 0.0025 -112 0.2705 0.2617 0 0 0 0.0021 -112.1 0.2709 0.2613 0 0 0 0.0017 -112.2 0.2705 0.261 0 0 0 0.0014 -112.3 0.271 0.2607 0 0 0 0.0012 -112.4 0.2723 0.2605 0 0 0 0.001 -112.5 0.2722 0.2603 0 0 0 0.0008 -112.6 0.2722 0.2602 0 0 0 0.0006 -112.7 0.2723 0.26 0 0 0 0.0005 -112.8 0.2706 0.2599 0 0 0 0.0004 -112.9 0.2691 0.2599 0 0 0 0.0003 -113 0.2688 0.2598 0 0 0 0.0003 -113.1 0.2688 0.2597 0 0 0 0.0002 -113.2 0.2682 0.2597 0 0 0 0.0002 -113.3 0.2679 0.2596 0 0 0 0.0001 -113.4 0.2687 0.2596 0 0 0 0.0001 -113.5 0.2687 0.2596 0 0 0 0.0001 -113.6 0.2687 0.2596 0 0 0 0.0001 -113.7 0.2696 0.2596 0 0 0 0 -113.8 0.2701 0.2595 0 0 0 0 -113.9 0.2705 0.2595 0 0 0 0 -114 0.2708 0.2595 0 0 0 0 -114.1 0.2719 0.2595 0 0 0 0 -114.2 0.2723 0.2595 0 0 0 0 -114.3 0.2739 0.2595 0 0 0 0 -114.4 0.2739 0.2595 0 0 0 0 -114.5 0.274 0.2595 0 0 0 0 -114.6 0.274 0.2595 0 0 0 0 -114.7 0.2739 0.2595 0 0 0 0 -114.8 0.2739 0.2595 0 0 0 0 -114.9 0.2724 0.2595 0 0 0 0 -115 0.2723 0.2595 0 0 0 0 -115.1 0.2713 0.2595 0 0 0 0 -115.2 0.2707 0.2595 0 0 0 0 -115.3 0.2709 0.2595 0 0 0 0 -115.4 0.2714 0.2595 0 0 0 0 -115.5 0.2714 0.2595 0 0 0 0