Database of Zeolite Structures
 

Framework Type CGS
Reference Material
  Material Name: Co-Ga-Phosphate-6    
 
Chemical Formula:
 
|(Quin)4 | [Co4Ga12P16O64]-CGS
Quin = C7H13N = quinuclidine = 1-azabicyclo[2.2.2]octane
SMILES: C1CN2CCC1CC2   Images:  stick or 3D
 
   
Unit Cell:
 
monoclinic

 P 1 21/c 1 (# 14)
    a' = 14.3650 Å b' = 16.3050 Å c' = 8.7340 Å  
    α' = 90.000° β' = 90.240° γ' = 90.000°  
(Relationship to unit cell of Framework Type: a' = b, b' = c, c' = a)
   
Framework Density:
 
15.6 T/1000 Å3
 
 
Channels:
 
{[001] 10 3.5 x 4.8 <-> [100] 8 2.5 x 4.6}***
Dimensionality
  Sorption (molecular cross section > 3.4Å): 1-dimensional
  Topological (pore opening > 6-ring): 3-dimensional
   
References:
  Cowley, A.R. and Chippindale, A.M.
  "CGS: cobalt and zinc gallophosphates with a new open-framework topology"
Microporous Mesoporous Mat., 28, 163-172 (1999)
 
 
Name and Code derivation:
    Cobalt-Gallium-Phosphate-six
  CoGaPO-6 (six)
  CGS
Limiting Rings
 
10-ring viewed along [001]

8-ring viewed along [100]