Database of Zeolite Structures
 
Framework Type ATO
31P MAS NMR spectrum of as-made AlPO-31 (with dipropylamine template)


Note: Toggle plots by clicking on the legend


Peak
Q-type
Chemical Shift
Relative
Peak Width
Peak Shape
Label
(ppm)
Peak Area
(ppm)
(x)L (1-x)G
A
Q4(4Al)
-35.34
1.000
1.19
0.489
B
Q4(4Al)
-33.87
1.000
1.19
0.489
C
Q4(4Al)
-33.43
1.000
1.19
0.489
D
Q4(4Al)
-33.04
1.000
1.19
0.489
E
Q4(4Al)
-32.37
1.000
1.19
0.489
F
Q4(4Al)
-32.06
1.000
1.19
0.489
G
Q4(4Al)
-31.85
1.000
1.19
0.489
H
Q4(4Al)
-31.24
1.000
1.19
0.489
I
Q4(4Al)
-30.54
1.000
1.19
0.489
J
Q4(4Al)
-30.06
1.000
1.19
0.489
K
Q4(4Al)
-29.50
1.000
1.19
0.489
L
Q4(4Al)
-28.82
1.000
1.19
0.489
M
Q4(4Al)
-28.66
1.000
1.19
0.489
N
Q4(4Al)
-28.12
1.000
1.19
0.489
O
Q4(4Al)
-25.13
1.000
1.19
0.489
P
Q4(4Al)
-25.03
1.000
1.19
0.489
Q
Q4(4Al)
-23.85
1.000
1.19
0.489
R
Q4(4Al)
-23.15
1.000
1.19
0.489



References
Spectrum

  Authors: Mali, G., Meden, A., Ristic, A., Tusar, N.N., Kaucic, V.
  Title: Interaction of dipropylamine template molecules with the framework of as-synthesized AlPO4-31
  Reference: J. Phys. Chem. B, 106, 63-69 (2002)
DOI: 10.1021/jp012942b
  Figure: Figure 3  

Digitization and Modeling of Spectrum

  To reference this collection of solid-state NMR spectra, we suggest:
  Authors: Brouwer, D.H. and White, A.L.
  Title: A comprehensive collection of solid-state 31P NMR spectra of aluminophosphate zeolites.
  Reference: Microporous Mesoporous Mat., 337, 111934 (2022)
DOI: 10.1016/j.micromeso.2022.111934
Spectrum information

  Obs. freq. 242.89 MHz (Field = 14.1 Tesla)
  Pulse sequence single pulse
  MAS frequency 11 kHz
  Spectrum Digitized and processed by Brouwer Lab, Redeemer University
  Data processing Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook
 
  CommentNo corresponding crystal structure is available

Chemical Formula

  [Al - P - O]-ATO

Downloads

  Download digitized spectrum in JCAMP-DX format
(This file includes also the data listed on this page)
  Download all lines from the above plot in .csv format
(This file contains only the plotted data)