Database of Zeolite Structures
 
Framework Type FER
29Si MAS NMR spectrum of calcined pure silica Ferrierite


Note: Toggle plots by clicking on the legend


Peak
T site
Q-type
Chemical Shift
Relative
Peak Width
Peak Shape
Assigment
(topological)
(ppm)
Peak Area
(ppm)
(x)L (1-x)G
Si4
T1
Q4(0Al)
-117.17
2.000
0.18
1.000
Si1
T4
Q4(0Al)
-116.44
1.000
0.22
1.000
Si5
T2
Q4(0Al)
-116.21
2.000
0.24
1.000
Si2
T3
Q4(0Al)
-112.44
2.000
0.15
1.000
Si3
T1
Q4(0Al)
-111.99
2.000
0.25
1.000



References
Spectrum

  Authors: Lewis, J.E., Freyhardt, C.C., Davis, M.E.
  Title: Location of pyridine guest molecules in an electroneutral {3∞}[SiO4/2] Host framework - single-crystal structures of the as-synthesized and calcined forms of high-silica ferrierite
  Reference: J. Phys. Chem., 100, 5039-5049 (1996)
DOI: 10.1021/jp9530055
  Figure: Figure 8  

Peak Assignment

  Authors: Lewis, J.E., Freyhardt, C.C., Davis, M.E.
  Title: Location of pyridine guest molecules in an electroneutral {3∞}[SiO4/2] Host framework - single-crystal structures of the as-synthesized and calcined forms of high-silica ferrierite
  Reference: J. Phys. Chem., 100, 5039-5049 (1996)
DOI: 10.1021/jp9530055
  Method: Relative intensities and bond angles

Crystal Structure

  Authors: Lewis, J.E., Freyhardt, C.C., Davis, M.E.
  Title: Location of pyridine guest molecules in an electroneutral {3∞}[SiO4/2] Host framework - single-crystal structures of the as-synthesized and calcined forms of high-silica ferrierite
  Reference: J. Phys. Chem., 100, 5039-5049 (1996)
DOI: 10.1021/jp9530055

Digitization and Modeling of Spectrum

  To reference this collection of solid-state NMR spectra, we suggest:
  Authors: Brouwer, D.H., Brouwer, C.C., Mesa, S., Semelhago, C.A., Steckley, E.E., Sun, M.P.Y., Mikolajewski, J.G., and Baerlocher, Ch.
  Title: Solid-state 29Si NMR spectra of pure silica zeolites for the International Zeolite Association Database of Zeolite Structures
  Reference: Microporous Mesoporous Mat., 297, 110000 (2020)
DOI: 10.1016/j.micromeso.2020.110000
Spectrum information

  Obs. freq. 59.63 MHz (Field = 7.1 Tesla)
  Pulse sequence single pulse
  MAS frequency 3.5 kHz
  Spectrum Digitized and processed by Brouwer Lab, Redeemer University
  Data processing Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook
 

Chemical Formula

  [Si - O]-FER

Downloads

  Download digitized spectrum in JCAMP-DX format
(This file includes also the data listed on this page)
  Download all lines from the above plot in .csv format
(This file contains only the plotted data)