Database of Zeolite Structures
 
Framework Type SAT
31P MAS NMR spectrum of as-made STA-2 (with bis-diazabicyclooctane-butane template)


Note: Toggle plots by clicking on the legend

Peak
Q-type
Chemical Shift
Relative
Peak Width
Peak Shape
Label
(ppm)
Peak Area
(ppm)
(x)L (1-x)G
A
Q4(4Al)
-34.06
1.00
2.42
0.000
B
Q4(4Al)
-32.60
1.00
2.42
0.000
C
Q4(4Al)
-31.21
1.00
2.42
0.000
D
Q4(4Al)
-28.24
1.00
2.93
0.000
E
Q4(4Al)
-28.14
1.00
2.93
0.000
F
Q4(4Al)
-28.04
1.00
2.93
0.000
G
Q4(4Al)
-27.94
1.00
2.93
0.000
H
Q4(4Al)
-27.84
1.00
2.93
0.000
I
Q4(4Al)
-27.74
1.00
2.93
0.000
J
Q4(4Al)
-24.80
1.00
3.67
0.000
K
Q4(4Al)
-24.49
1.00
3.67
0.000
L
Q4(4Al)
-21.95
1.00
3.67
0.000


References
Spectrum

  Authors: Castro, M., Seymour, V.R., Carnevale, D., Griffin, J.M., Ashbrook, S.E., Wright, P.A., Apperley, D.C., Parker, J.E., Thompson, S.P., Fecant, A., Bats, N.
  Title: Molecular modeling, multinuclear NMR, and diffraction studies in the templated synthesis and characterization of the aluminophosphate molecular sieve STA-2
  Reference: Journal of Physical Chemistry C, 114, 12698-12710 (2010
DOI: 10.1021/jp104120y)
  Figure: Figure 5d  

Crystal Structure

  Authors: Castro, M., Seymour, V.R., Carnevale, D., Griffin, J.M., Ashbrook, S.E., Wright, P.A., Apperley, D.C., Parker, J.E., Thompson, S.P., Fecant, A., Bats, N.
  Title: Molecular modeling, multinuclear NMR, and diffraction studies in the templated synthesis and characterization of the aluminophosphate molecular sieve STA-2
  Reference: Journal of Physical Chemistry C, 114, 12698-12710 (2010)
DOI: 10.1021/jp104120y

Digitization and Modeling of Spectrum

  To reference this collection of solid-state NMR spectra, we suggest:
  Authors: Brouwer, D.H. and White, A.L.
  Title: A comprehensive collection of solid-state 31P NMR spectra of aluminophosphate zeolites.
  Reference: Microporous Mesoporous Mat., 337, 111934 (2022)
DOI: 10.1016/j.micromeso.2022.111934
Spectrum information

  Obs. freq. 242.9 MHz (Field = 14.1 Tesla)
  Pulse sequence single pulse
  MAS frequency 14 kHz
  Spectrum Digitized and processed by Brouwer Lab, Redeemer University
  Data processing Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook
 
  CommentPeak assignments are not available

Chemical Formula

  [Al - P - O]-SAT

Downloads

  Download digitized spectrum in JCAMP-DX format
(This file includes also the data listed on this page)
  Download all lines from the above plot in .csv format
(This file contains only the plotted data)

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