Database of Zeolite Structures
 
Framework Type SOD
31P MAS NMR spectrum of as-made AlPO-SOD (with dimethylformamide template)


Note: Toggle plots by clicking on the legend

Peak
T site
Q-type
Chemical Shift
Relative
Peak Width
Peak Shape
Assigment
(topological)
(ppm)
Peak Area
(ppm)
(x)L (1-x)G
P2
T1
Q4(4Al)
-34.08
1.000
2.11
0.296
P3
T1
Q4(4Al)
-28.20
1.000
1.66
0.296
P1
T1
Q4(4Al)
-23.17
1.000
1.48
0.296


References
Spectrum

  Authors: Vidal, L., Paillaud, J.L., Gabelica, Z.
  Title: A novel monoclinic AlPO4-sodalite formed in the presence of dimethylformamide as template and solvent
  Reference: Microporous Mesoporous Mater., 24, 189-197 (1998)
  Figure: Figure 5  

Peak Assignment

  Authors: Roux, M., Marichal, C., Paillaud, J.L., Fernandez, C., Baerlocher, C., Chezeau, J.M.
  Title: Structural investigation by multinuclear solid state NMR and X-ray diffraction of as-synthesized, dehydrated, and calcined AlPO4-SOD
  Reference: J. Phys. Chem. B, 105, 9083-9092 (2001)
  Method: 2D correlation NMR
  Figure: Figure 7 and 9  

Crystal Structure

  Authors: Roux, M., Marichal, C., Paillaud, J.L., Fernandez, C., Baerlocher, C., Chezeau, J.M.
  Title: Structural investigation by multinuclear solid state NMR and X-ray diffraction of as-synthesized, dehydrated, and calcined AlPO4-SOD
  Reference: J. Phys. Chem. B, 105, 9083-9092 (2001)

Digitization and Modeling of Spectrum

  To reference this collection of solid-state NMR spectra, we suggest:
  Authors: Brouwer, D.H. and White, A.L.
  Title: A comprehensive collection of solid-state 31P NMR spectra of aluminophosphate zeolites.
  Reference: Microporous Mesoporous Mat., 337, 111934 (2022)
Spectrum information

  Obs. freq. 121.5 MHz (Field = 7 Tesla)
  Pulse sequence single pulse
  MAS frequency 5 kHz
  Spectrum Digitized and processed by Brouwer Lab, Redeemer University
  Data processing Spectrum digitized with WebPlotDigitizer and deconvoluted with Mathematica notebook
 
  CommentPeak assignments based on 2D 27Al/31P and 31P/31P correlation spectra

Chemical Formula

  [Al - P - O]-SOD

Downloads

  Download digitized spectrum in JCAMP-DX format
(This file includes also the data listed on this page)
  Download all lines from the above plot in .csv format
(This file contains only the plotted data)

Copyright © 2017 Structure Commission of the International Zeolite Association (IZA-SC)